面向CH4-CO2重整反应的生物质炭基催化剂载体制备工艺的研究进展

Research progress on the preparation process of biochar-based catalyst support for dry reforming of methane

  • 摘要: CH4干重整(DRM)技术能够同时将CH4和CO2两种温室气体转化为合成气,以实现温室气体减排及资源化利用,因此,越来越受到研究者的青睐。生物质炭具有高比表面积、发达的孔隙结构、高的热稳定性、优异的耐酸碱性、丰富的碱/碱土金属和含氧官能团含量以及成本低廉等优点,其应用于DRM,可以适用于页岩气、油田伴生气、焦炉煤气和煤层气等不同的重整体系,省去部分废气的脱硫等预处理过程,具有重要的工业应用前景。本工作对用于DRM的生物质炭基催化剂载体的制备工艺进行了总结。综述了不同的炭化工艺及其对生物质炭产量和性质的影响;介绍了生物质炭的理化性质对重整反应的影响及影响理化性质的因素;分析了不同的活化方法对生物质炭基催化剂催化性能的影响;并对影响催化剂稳定性的碳消耗进行了介绍。

     

    Abstract: Dry reforming of methane (DRM) technology, converting two kinds of greenhouse gases (CH4 and CO2) into syngas to achieve greenhouse gas emission reduction and resource utilization, has attracted more and more attention from researchers. Due to the advantages of high specific surface area, developed porous structure, high thermal stability, excellent acid and alkali resistance, abundant content of alkali/alkaline earth metals and oxygen-containing functional groups, and low cost, bio-char is suitable for different DRM systems, including shale gas, oil field associated gas, coke oven gas and coal bed methane systems, which can avoid some pretreatment processes such as desulfurization of part of the exhaust. Therefore, bio-char may offer attractive prospects for large-scale DRM industrial applications. Herein, the review briefly summarizes the preparation process of biochar-based catalyst supports for DRM. The different carbonization procedures and their effects on the yield and properties of bio-char are briefly described. The advantages and influence factors of the physicochemical property of bio-char in the reforming reaction are introduced. The influence of different activation methods on the catalytic performance of biochar-based catalysts is also analyzed. Finally, the carbon consumption that affects the stability of the catalyst is briefly introduced.

     

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