应用溶解度参数理论筛选柴油萃取脱蜡的溶剂

应用溶解度参数理论筛选柴油萃取脱蜡的溶剂

  • 摘要: 采用基团贡献法分别计算了酮类、氯代烃类、酯类、醇类和醚类溶剂的色散溶解度参数(δd)、极性溶解度参数(δp)和氢键溶解度参数(δh),并分析了柴油组分中正构烷烃和芳烃的三维溶解度参数的特点。研究了溶剂溶解度参数与其萃取柴油脱蜡效果的关系。结果表明,除了醇类溶剂之外,在参数贡献图中距离正构烷烃距离越远的溶剂,正构烷烃得率越大,萃取效果越好;色散力贡献比大于2/3的溶剂萃取时蜡膏的含油量明显低于色散力贡献比小于2/3的溶剂。

     

    Abstract: The solubility parameters (including dispersion coefficient δd, polarity δp, and hydrogen bonding δh) of extraction solvents (like ketones, chlorinated hydrocarbon, ester, alcohol, and ether) and diesel oil components (n-alkanes and aromatics) were estimated by using the group contribution method. The relationship between the solubility parameters of the solvent and the extraction efficiency of nalkane from diesel oil was investigated. The results illustrated that the larger the difference between the solvent and nalkane in the solubility parameters is, the higher is the extraction ratio, for the solvents except alcohols. Nonalkane content of waxpaste removed by the solvents with a dispersion contribution (fd) of higher than twothirds was much less than that by the solvents with a lower fd.

     

/

返回文章
返回