水对两段法合成汽油中HZSM-5分子筛稳定性及油相产物的影响

Effect of water on stability of |HZSM-5 and product distribution in two-stage gasoline synthesis from syngas

  • 摘要: 模拟两段法合成汽油工艺的反应条件(360℃、2MPa),通过控制甲醇的脱水量或在该气氛下对HZSM-5进行水热预处理,考察了水对催化剂稳定性及油相产物的影响。XRD、BET、FT-IR、SEM和NH3-TPD等表征手段表明水热预处理后的分子筛具有晶粒小、中孔多和酸强度低等特点,能显著提高汽油收率和异构烷烃选择性。甲醇在HZSM-5分子筛上发生脱水反应,产生的水热气氛造成强酸中心失活。

     

    Abstract: The effects of water on the stability of the catalyst and the product distribution were investigated through controlling the amount of water dehydrated from methanol or using HZSM5 pretreated by hydrothermal method at the analogous atmosphere of gasoline synthesis in two-stage process(360℃, 2MPa). Physicochemical properties of the zeolite were characterized by XRD, BET, FT-IR, SEM, and NH3-TPD. The results showed that HZSM-5 pretreated by hydrothermal method had smaller crystal size, more mesoporous, and moderate acid sites, which in all result in the enhancement of gasoline yield and the selectivity to iso-paraffins. The steam generated during methanol dehydration led to the deactivation of strong acid over HZSM-5 zeolite.

     

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