中国煤中磷的分布特征

Distribution of phosphorus in Chinese coals

  • 摘要: 以“中国煤种资源数据库”为基础,结合新采集煤样,对中国不同煤田1117个煤层煤样的磷含量数据进行了统计分析。结果表明,中国煤中磷可采储量加权平均质量分数为224×10-6,大约90%的煤中磷质量分数低于500×10-6,为特低磷煤或低磷煤,全国总体上呈“北低南高”的趋势。按不同聚煤区、不同成煤时代和不同煤炭类别讨论了中国煤中磷的分布特征。结果表明,南方的江西、湖南、四川、云南和福建等省的三叠纪煤磷元素含量最高。通过中国煤中磷含量与其他因素的相关性分析表明,中国煤中磷含量与硫分、形态硫、灰分、灰成分等因素相关均不密切,锶、氟与磷的相关系数明显高于其他微量元素。

     

    Abstract: The phosphorus content in Chinese coals was studied based on 1117 coal samples from Chinese Coal Resource Database and new sampling coals. The results show that the weighted mean content of phosphorus in Chinese coals is 224×10-6, about 90% of the phosphorus content of Chinese coal below 500×10-6 and belong to lower or super lower content, and the phosphorus content in southern China is higher than in northern China. The distribution of phosphorus in Chinese coal from different coal-accumulated area, different geological ages, and different classes of coals was discussed. The results show that the phosphorus content of coal in Triassic period from southern China (Jiangxi, Hunan, Sichuan, Yunan and Fujian provinces) is the highest. The relativities between the phosphorus content and other factors were analyzed. The results show that the phosphorus content of Chinese coal has no significant correlation with sulfur, forms of sulfur, ash and ash component, the correlation between phosphorus and strontium, fluorine are obviously higher than other elements in Chinese coals.

     

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