纳米二氧化钛光催化降解喹啉动力学
Kinetic study of photocatalytic degradation of quinoline over nanosized titanium dioxide
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摘要: 利用溶胶-凝胶法制备纳米二氧化钛光催化剂,探讨了其光催化降解废水中典型含氮杂环化合物喹啉的动力学行为。实验条件下,TiO2光催化降解喹啉的反应为准一级反应,可用Langmuir-Hinshelwood动力学模型描述,其表达式为r=0.296kct/(1+0.296ct),其中,lnk =-0.411 1lnc0+2.278。Abstract: Kinetics for photocatalytic degradation of quinoline over nanosized titanium dioxide prepared by sol-gel method was investigated. On the basis of Langmuir-Hinshelwood model, a kinetic equation for the quinoline degradation over TiO2 was proposed, which can be described as r = 0.296kct/(1+0.296ct), where lnk =-0.411 1 lnc0+2.278.