H2气氛下褐煤快速热解过程中CH4逸出规律的分析

Analysis of CH4 evolution in fast pyrolysis of lignite under H2 atmosphere

  • 摘要: 在带有输送煤样的管式反应器上进行了霍林河褐煤加压快速氢解实验,分析了H2对煤/半焦的化学键断裂和对CH4生成规律的影响。在加压快速氢解条件下,CH4产率随着热解温度升高、压力的增大而增大;在50% H2气氛下,操作压力为1.0 MPa、温度为900 ℃时,CH4产率为8.08%,达到最大,较N2气氛下的提高了72.5%。H2或H·自由基诱发了芳环的开裂、侧链、脂肪链和醚键的断裂,促进了煤热解。CH4产率的增加主要是由于外部供H的结果;热解温度低于700 ℃时,H2对煤结构中活性基团的作用促进了煤热解,导致了CH4产率的增加;而热解温度高于700 ℃后,煤/半焦加氢气化促进了CH4产率的增加。

     

    Abstract: The fast hydropyrolysis of Huolinhe lignite were carried out under pressure in a tubular reactor with a transporter for coal samples. The effect of H2 on CH4 evolution and crack of chemical bonds were analyzed. Under pressure fast hydropyrolysis conditions, CH4 yield was higher under H2 atmosphere than that under N2 atmosphere, and increased with increasing temperature and pressure. Compared with N2 atmosphere, the yield of CH4 increased by 72.5% under 50% H2 atmosphere at 900 ℃ and 1.0 MPa. H2 or H· free radical induced the cracks of aromatic rings, side chains, ether linkages and aliphatic chains in the char, which could promote the coal pyrolysis. The increased yield of CH4 was mainly due to the external donor H. Below 700 ℃, the action of H2 with active groups in coal structure affected the pyrolysis of coal; above 700 ℃, hydrogenation of char promoted coal pyrolysis, leading to an increase in CH4 yield.

     

/

返回文章
返回