Abstract:
The fast hydropyrolysis of Huolinhe lignite were carried out under pressure in a tubular reactor with a transporter for coal samples. The effect of H
2 on CH
4 evolution and crack of chemical bonds were analyzed. Under pressure fast hydropyrolysis conditions, CH
4 yield was higher under H
2 atmosphere than that under N
2 atmosphere, and increased with increasing temperature and pressure. Compared with N
2 atmosphere, the yield of CH
4 increased by 72.5% under 50% H
2 atmosphere at 900 ℃ and 1.0 MPa. H
2 or H· free radical induced the cracks of aromatic rings, side chains, ether linkages and aliphatic chains in the char, which could promote the coal pyrolysis. The increased yield of CH
4 was mainly due to the external donor H. Below 700 ℃, the action of H
2 with active groups in coal structure affected the pyrolysis of coal; above 700 ℃, hydrogenation of char promoted coal pyrolysis, leading to an increase in CH
4 yield.