劣质渣油性质对受热生焦趋势影响的研究

Effect of characteristics of inferior residues on thermal coke induction periods

  • 摘要: 以四种劣质渣油为原料,研究组成性质对其热转化过程初期生焦特性的影响。结果表明,不同油样生焦诱导期受温度改变的影响程度可以用敏感度参数衡量,生焦诱导期越短的油样,敏感度参数越大,反应温度升高其生焦诱导期降低率越大。相同反应条件下,劣质渣油的生焦特性取决于其自身的基本性质,且各个性质对其生焦特性的影响程度不一。残炭、灰分、分子量、沥青质沉淀点和稳定性参数与其生焦诱导期相关性较强,其中,沥青质沉淀点和稳定性参数均反映的是油样胶体稳定性的突出影响。劣质渣油自身的胶体稳定性与其生焦密切相关,胶体稳定性越差的渣油,越容易生焦,油样的生焦过程是热反应过程中胶体体系逐渐被破坏的过程。

     

    Abstract: Using 4 inferior residual oils as raw materials, the effect of feedstock properties on the characteristics of coke formation during initial thermal conversion process was studied.The results show that the influence for coke induction period of different oils affected by temperature can be measured with the sensitivity parameters.The shorter the coke induction period of the residue, the bigger the sensitivity parameter.The coke induction period has a higher decrease rate with the reaction temperature rising.The coke formation property generally depends on feedstock's basic properties, and the influence of various properties of inferior residual oils on coke formation is different under the same reaction conditions.Carbon residue, ash, relative molecular mass, asphaltene precipitation onset point and stability parameter have strong correlations with the coke induction period, especially for the colloidal stability of oil reflected by asphaltene precipitation onset point and stability parameter.The colloidal stability of the inferior residual oils is related to the coke formation characteristics.The worse the stability of the residue, the more likely the coke is to form.The coke forming process is a gradual destruction of the colloid system during thermal reaction.

     

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