燃煤烟气非碳基吸附剂脱汞研究进展

Research progress on the removal of mercury from coal-fired flue gas by using non-carbon-based adsorbents

  • 摘要: 燃煤烟气排放的汞严重危害人体健康及生态环境。本研究首先分析了超低排放燃煤电厂烟气汞排放特征,尤其是脱硝、除尘、脱硫设备超低排放改造后烟气汞的形态分布和迁移转化规律;然后总结了近年来用于燃煤烟气净化的非碳基吸附剂的研究进展,归纳了飞灰、矿物吸附剂、贵金属、金属氧化物和金属硫化物的吸附性能,并对影响其吸附性能的常见因素进行了梳理。基于当前研究进展,提出了未来的研究应关注的含汞废吸附剂上汞的稳定性和浸出毒性以及吸附剂的再生和循环利用等问题。

     

    Abstract: Mercury emitted from coal-fired power plants seriously harms human health and the ecological environment. In this paper, the effect of pollutant control devices on the removal of mercury from the flue gas in the ultra-low emission coal-fired power plants were first summarized; in particular, the impact of denitration, dedusting, and desulfuration devices after the ultra-low emission retrofits on the mercury removal was highlighted. Subsequently, the research progress on the non-carbon-based adsorbents used in the flue gas cleaning, including fly ash, natural minerals, noble metals, metal oxides, and metal sulfides, was then reviewed; the factors that may influence their performance in mercury adsorption were evaluated. Lastly, based on the current research progress, it is proposed that special attention should be paid in the future to the stability and leaching toxicity of adsorbed mercury as well as the regeneration and recycling of the spent adsorbents.

     

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